NOTE: This is the S5-868A2L00 which works with a fixed code on 868.3MHz. There is also a S5-433A2L00 which works with a fixed code on 433.92MHz. Aside from that, there are also 2 version with blue buttons that work with rolling codes. None of these remotes are compatible.
Programming your remote: Program directly to the receiver. Consult the manual of your controller/opener/receiver.